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ChemInform Abstract: Ethynyl MIDA Boronate: A Readily Accessible and Highly Versatile Building Block for Small Molecule Synthesis.

✍ Scribed by Justin R. Struble; Suk Joong Lee; Martin D. Burke

Publisher: John Wiley and Sons
Year: 2010
Weight: 47 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201045173

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✦ Synopsis

Abstract

Ethynyl N‐methyliminodiacetic acid boronate (I) is successfully applied in the regioselective iterative synthesis of arylethyne (III) and tolan derivatives, e.g. (IV).

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ChemInform Abstract: (Z)-(2-Bromovinyl)-

ChemInform Abstract: (Z)-(2-Bromovinyl)-MIDA Boronate: A Readily Accessible and Highly Versatile Building Block for Small Molecule Synthesis.

✍ Eric M. Woerly; Justin R. Struble; Nagarjuna Palyam; Sean P. O'Hara; Martin D. B 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 58 KB 👁 1 views

## Abstract The synthesis of the bifunctional (Z)‐olefin building block (II) is developed and the utility the product in a variety of Pd‐catalyzed cross‐coupling reactions is demonstrated.