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ChemInform Abstract: Vinylogous Wolff Rearrangement of β,γ-Unsaturated α- Diazo-β-ketoesters: A Novel Method for the Preparation of Substituted Malonates.

✍ Scribed by P. CECCHERELLI; M. CURINI; F. EPIFANO; M. C. MARCOTULLIO; O. ROSATI

Book ID
112022314
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
26
Category
Article
ISSN
0931-7597

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A novel synthetic method for angularly f
A novel synthetic method for angularly functionalized polycyclic systems by vinylogous wolff rearrangement of β, γ-unsaturated diazoketones
✍ Bijali Saha; Gopa Bhattacharjee; Usha Ranjan Ghatak 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 168 KB

Decompositions of the rigid polycylic &y-unsaturated diasomethyl ketones c&g and i) and ($ and,&) promoted by Cu(acacj2, Cu(OTf)2, Ni(acacj2 or silver benzoatetriethylamine in the presence of methanol are shown to give the respective rearranged y,&unsaturated angularly substituted esters (2~ and b)