The title iodonium triflates (I) and (II) are decomposed in CHCl 3 at 20-35 โข C to give a stereoisomeric mixture of six enol triflates, as result of heterolytic C-I bond cleavage followed by direct TfO -trapping of the generated primary vinyl cation (III). Incorporation of strongly electron-withdraw
โฆ LIBER โฆ
ChemInform Abstract: Vinyl Carbocations: Solution Studies of Alkenyl(aryl)iodonium Triflate Fragmentations.
โ Scribed by Anne J. McNeil; Robert J. Hinkle; E. Ashley Rouse; Quinn A. Thomas; David B. Thomas
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 25 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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