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ChemInform Abstract: New One-Pot Method for the Stereoselective Synthesis of (E)-[β-(Trifluoromethylsulfonyloxy)-alkenyl](aryl) Iodonium Triflates.

✍ Scribed by T. M. KASUMOV; N. SH. PIRGULIYEV; V. K. BREL; YU. K. GRISHIN; N. S. ZEFIROV; P. J. STANG

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

New One-Pot Method for the Stereoselective Synthesis of (E)-β-(Trifluoromethylsulfonyloxy)-alkenyl Iodonium Triflates. -The reaction proceeds via aryl(fluoro)iodonium triflate intermediates. The title compounds can serve as reactive substrates in vinylic nucleophilic substitution reactions and as synthons of vinyl cations. -(KASUMOV, T. M.;

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