ChemInform Abstract: New One-Pot Method for the Synthesis of Alkynyl Sulfonate Esters Using Ultrasound.
β Scribed by Atilla Tuncay; Beth M. Anaclerio; Melissa Zolodz; Kenneth S. Suslick
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
New One-Pot Method for the Synthesis of Alkynyl Sulfonate Esters Using Ultrasound. -Alkynyl sulfonates esters (III) are directly obtained by the coupling of terminal alkynes with hypervalent iodo compounds in the presence of AgOTf. Ultrasonic irradiation results in a remarkable increase in reactivity due to rapid dispersion of the insoluble iodobenzenes. -(TUN-
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
New One-Pot Method for the Stereoselective Synthesis of (E)-[Ξ²-(Trifluoromethylsulfonyloxy)-alkenyl](aryl) Iodonium Triflates. -The reaction proceeds via aryl(fluoro)iodonium triflate intermediates. The title compounds can serve as reactive substrates in vinylic nucleophilic substitution reactions a