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ChemInform Abstract: Unusual Chlorination of Some Olefins with meta-Chloroperbenzoic Acid in Dichloromethane.

✍ Scribed by M. LAKHRISSI; G. CARCHON; T. SCHLAMA; C. MIOSKOWSKI; Y. CHAPLEUR

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199847246

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✦ Synopsis

Unusual Chlorination of Some Olefins with meta-Chloroperbenzoic Acid in Dichloromethane.

-In the presence of poorly reactive olefins such as carbohydrate-derived dichloro compounds, meta-chloroperbenzoic acid reacts with dichloromethane to produce a powerful chlorination reagent that reacts like other chlorinating agents. Carbohydrates protected with benzyl groups do not react.

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