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ChemInform Abstract: Unusual 1,4-Addition of 2-Pyridyl Carboxylates to Benzynes: A Convenient Route to 1-(2-Acylphenyl)-2-pyridones.

โœ Scribed by Dinesh Kumar Rayabarapu; Kanak Kanti Majumdar; Thota Sambaiah; Chien-Hong Cheng


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
32
Category
Article
ISSN
0931-7597

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โœ David W. Piotrowski ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 1 views

A Concise Route to Novel 1-Aryl and 1-Pyridyl-2azabicycylo[2.1.1]hexanes. -Sensitized photolysis of readily prepared ene-carbamates (III) results in intramolecular [2 + 2] cycloaddition to azabicyclo[2.1.1]hexanes (IV). The products [cf. (IVc)] can be further converted to analogues (V) of 2,4-metha