ChemInform Abstract: Unprecedented Copper(I)-Catalyzed Photochemical Reaction of Diethyl Ether with Vicinal Diols and Ketals.
β Scribed by Sujit Mondal; Ram Naresh Yadav; Subrata Ghosh
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 23 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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The Reaction of Polyhalides with Allylsilanes Catalyzed by Copper(I) Chloride. -Allyltrimethylsilane (I) reacts with polyhalogen compounds (II) in the presence of copper species affording polyhalo compounds containing an allyl group. Other allylsilanes, e.g. (IV), (VI), and (IX), give various produ