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ChemInform Abstract: Ultrasound-Promoted Deoxygenation of Sulfoxides by Samarium—NH4Cl.

✍ Scribed by Jhillu S. Yadav; Basi V. Subba Reddy; C. Srinivas; P. Srihari


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
32
Category
Article
ISSN
0931-7597

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A Novel Cyclodimerization of Arylidenecyanoacetate Promoted by Samarium Diiodide. -Reductive treatment of arylidenecyanoacetates with SmI 2 results in cyclodimerization to the aminocyclopentenes (II). However, the hydroxyphenyl-substituted substrate yields only the double bond reductive product (VI