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ChemInform Abstract: Two New Neptunyl(V) Selenites: A Novel Cation—Cation Interaction Framework in (NpO2)3(OH)(SeO3) (H2O)2·H2O and a Uranophane-Type Sheet in Na(NpO2)(SeO3)(H2O).

✍ Scribed by Geng Bang Jin; S. Skanthakumar; L. Soderholm


Publisher
John Wiley and Sons
Year
2011
Weight
29 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The structures of the new compounds (III) and (V) are determined by single crystal XRD.


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ChemInform Abstract: Cation—Cation Inter
✍ Geng Bang Jin; S. Skanthakumar; L. Soderholm 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 23 KB 👁 1 views

Cation-Cation Interactions: Crystal Structures of Neptunyl(V) Selenate Hydrates, (NpO2)2(SeO4)(H2O)n (n = 1, 2, and 4). -Green crystals of (NpO2)2(SeO4)(H2O)4 (I), (NpO2)2(SeO4)(H2O)2 (II), and (NpO2)2(SeO4)(H2O) (III) are hydrothermally synthesized from mixtures of Na2SeO4 in 2 M aq. NaOH and in 0.