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ChemInform Abstract: Tunable Stereoselective Alkene Synthesis by Treatment of Activated Imines with Nonstabilized Phosphonium Ylides.

โœ Scribed by De-Jun Dong; Yuan Li; Jie-Qi Wang; Shi-Kai Tian


Publisher
John Wiley and Sons
Year
2011
Weight
35 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Reaction of Monocar
โœ M. OCHIAI; Y. KITAGAWA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 36 KB ๐Ÿ‘ 2 views

Reaction of Monocarbonyl Iodonium Ylides with Activated Imines: Stereoselective Synthesis of trans-and cis-ฮฑ,ฮฒ-Aziridino Ketones. -Treatment of iodonium salts (I) with lithium ethoxylate generates monocarbonyl iodonium ylides which readily undergo alkylidene-transfer reactions with activated imines.