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ChemInform Abstract: Triphenylphosphine/Scandium(III) Trifluoromethanesulfonate: A New Agent for the Reformatsky Reaction of α-Bromo Carboxylic Acid Derivatives with Aldehydes.

✍ Scribed by H. KAGOSHIMA; Y. HASHIMOTO; K. SAIGO


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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Triphenylphosphine/scandium(III) trifluo
✍ Hirotaka Kagoshima; Yukihiko Hashimoto; Kazuhiko Saigo 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 136 KB

The Ph3P/Sc(OTf)3 combination was found to be effective for the Reformatsky reaction; when ~-bromo carboxylic acid derivatives were allowed to react with aldehydes in the presence of the Ph3P/Sc(OTf) 3 combination, the corresponding [3-hydroxy carboxylic acid derivatives were obtained in good yields