ChemInform Abstract: Trifluoroacetaldehyde: A Useful Industrial Bulk Material for the Synthesis of Trifluoromethylated Amino Compounds.
β Scribed by Hideyuki Mimura; Kosuke Kawada; Tetsuya Yamashita; Takeshi Sakamoto; Yasuo Kikugawa
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 41 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
The application of the title compound for the synthesis of trifluoromethylated amino compounds via reductive amination reactions, and in the synthesis of chiral Ξ±βsubstituted trifluoroethylamino compounds via chiral sulfinimine (X) is reported.
π SIMILAR VOLUMES
Electroorganic Chemistry. Part 155. Electroreductive Coupling of Aliphatic Amides. A Useful Method for the Synthesis of Ξ±-Amino Ketones. -Cathodic reduction of aliphatic amides (I) in the presence of trimethylsilyl chloride (II) using magnesium electrodes is described. The enol ether coupling produ