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ChemInform Abstract: Trifluoroacetaldehyde: A Useful Industrial Bulk Material for the Synthesis of Trifluoromethylated Amino Compounds.

✍ Scribed by Hideyuki Mimura; Kosuke Kawada; Tetsuya Yamashita; Takeshi Sakamoto; Yasuo Kikugawa


Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The application of the title compound for the synthesis of trifluoromethylated amino compounds via reductive amination reactions, and in the synthesis of chiral α‐substituted trifluoroethylamino compounds via chiral sulfinimine (X) is reported.


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ChemInform Abstract: Electroorganic Chem
✍ S. KASHIMURA; M. ISHIFUNE; Y. MURAI; H. MURASE; M. SHIMOMURA; T. SHONO πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB

Electroorganic Chemistry. Part 155. Electroreductive Coupling of Aliphatic Amides. A Useful Method for the Synthesis of Ξ±-Amino Ketones. -Cathodic reduction of aliphatic amides (I) in the presence of trimethylsilyl chloride (II) using magnesium electrodes is described. The enol ether coupling produ