## Abstract Catalytic properties of a series of chiral (pyrrolidine salen)Mn(III) complexes for asymmetric oxidation of aryl methyl sulfides were evaluated. Moderate activity, good chemical selectivity and low enantioselectivity were attained with iodosylbenzene as a terminal oxidant. Enantioselect
ChemInform Abstract: Trapping of the Dichlorocarbonyl Oxide Using a Chiral (Salen)Mn(III) Complex.
β Scribed by N. H. LEE; J. S. BAIK; S. HAN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Trapping of the Dichlorocarbonyl Oxide Using a Chiral (Salen)Mn(III) Complex.
-The title trapping reaction in the presence of alkenes leads to chiral epoxides. The total conversion of starting material is 14-58% and the best ratio of epoxide to cyclopropane is 2.5 (no yields given). -(LEE, N.
π SIMILAR VOLUMES
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