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ChemInform Abstract: (Salen)Mn(III) Catalyzed Oxidation of Alcohols Using Sodium Hypochlorite as an Oxidant.

✍ Scribed by N. H. LEE; J. S. BAIK; S. HAN

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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Trapping of the Dichlorocarbonyl Oxide Using a Chiral (Salen)Mn(III) Complex. -The title trapping reaction in the presence of alkenes leads to chiral epoxides. The total conversion of starting material is 14-58% and the best ratio of epoxide to cyclopropane is 2.5 (no yields given). -(LEE, N.