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ChemInform Abstract: Transition Metal Promoted Synthesis of N,N-Dimethyl Tertiary Amides from 1,3-Dienes.

โœ Scribed by J. SZYMONIAK; D. FELIX; C. MOISE

Book ID
112031142
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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A Convenient Access to N,N-Disubstituted Amides Derived from (1R,3S)-(-)-2,2-Dimethyl-3-formylcyclopropane-1-carboxylic Acid. -The enantiopure title amides are obtained in three steps from biocartol (I). Deprotection of the mono-N-substituted amides did not give the expected aldehydes such as (VII)