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ChemInform Abstract: Transition Metal-Diene Complexes in Organic Synthesis. Part 28. Asymmetric Catalysis in the Complexation of Prochiral Dienes by the Tricarbonyliron Fragment: A Novel Methodology for the Enantioselective Synthesis of Planar Chiral Tricarbonyl(diene)iron Complexes.

✍ Scribed by H.-J. KNOELKER; H. HERMANN

Book ID
112032148
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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L-Amino acid esters as chiral auxiliaries in the asymmetric complexation of 1-methoxycyclohexa-l,3-diene with pentacarbonyliron afford the R-enantiomer of the corresponding planar chiral tricarbonylimn complex in up to 24% ee.