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ChemInform Abstract: Transition-Metal Chloride Mediated Addition Reaction of Diorganomagnesium to Easily Enolizable Ketones.

✍ Scribed by Mutsumi Sada; Seijiro Matsubara

Publisher
John Wiley and Sons
Year
2011
Weight
24 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

A combination of organylmagnesium reagent with FeCl~2~ or YbCl~3~ generates a complex reagent that undergoes nucleophilic addition to enolizable ketones like α‐tetralone (I) prior to enolization.

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