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ChemInform Abstract: Samarium Diiodide Mediated Reductive Addition Reaction of 1-(Phenylsulfonylmethyl) Benzotriazole and 1-(Benzoyloxymethyl) Benzotriazole to Aldehydes and Ketones.

✍ Scribed by Zhifang Li; Yongmin Zhang

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200223141

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Diverse Cycloaddition Chemistry Leading to Overall Michael Addition in the Reactions of 1,1-Bis(dimethylamino)-2,2-difluoroethene with α,β-Unsaturated Aldehydes, Ketones, Esters, and Nitriles. -The freshly prepared difluoro ketene aminal (I) reacts with α,β-unsaturated aldehydes or ketones via [4 +