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ChemInform Abstract: Transition-Metal-Catalyzed Regioselective Aroyl- and Trifluoro-acetylthiolation of Alkynes Using Thioesters.

โœ Scribed by Yasunori Minami; Hitoshi Kuniyasu; Kiyoshi Miyafuji; Nobuaki Kambe

Publisher
John Wiley and Sons
Year
2009
Weight
49 KB
Volume
40
Category
Article
ISSN
0931-7597

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Transition Metal Catalyzed Regioselective and Stereoselective Aminochlorination of Cinnamic Esters. -Cinnamic esters (I) react with N,N-dichloro-p-tosylamide in the presence of catalytic ZnCl 2 or Cu(O-Tf) 2 to undergo an aminohalogenation process providing the vicinal haloamine derivatives (III) c