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ChemInform Abstract: Transition Metal Catalyzed Regioselective and Stereoselective Aminochlorination of Cinnamic Esters.

✍ Scribed by Guigen Li; Han-Xun Wei; Sun Hee Kim; Margret Neighbors


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Transition Metal Catalyzed Regioselective and Stereoselective Aminochlorination of Cinnamic Esters.

-Cinnamic esters (I) react with N,N-dichloro-p-tosylamide in the presence of catalytic ZnCl 2 or Cu(O-Tf) 2 to undergo an aminohalogenation process providing the vicinal haloamine derivatives (III) completely regio-and diastereoselectively. - (LI, GUIGEN;


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