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ChemInform Abstract: Transition Metal Catalyzed [5 + 2] Cycloadditions of Allenes and Vinylcyclopropanes: First Studies of endo—exo Selectivity, Chemoselectivity, Relative Stereochemistry, and Chirality Transfer.

✍ Scribed by Paul A. Wender; Frank Glorius; Craig O. Husfeld; Elke Langkopf; Jennifer A. Love

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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Abstract

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ChemInform Abstract: The First Metal-Catalyzed Intramolecular [5 + 2] Cycloadditions of Vinylcyclopropanes and Alkenes: Scope, Stereochemistry, and Asymmetric Catalysis.
✍ P. A. WENDER; C. O. HUSFELD; E. LANGKOPF; J. A. LOVE; N. PLEUSS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 2 views

The First Metal-Catalyzed Intramolecular [5 + 2] Cycloadditions of Vinylcyclopropanes and Alkenes: Scope, Stereochemistry, and Asymmetric Catalysis. -This novel cycloaddition works well with a wide variety of substrates, and generally proceeds with exceptional diastereoselectivity and in good to exc