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ChemInform Abstract: The First Metal-Catalyzed Intramolecular [5 + 2] Cycloadditions of Vinylcyclopropanes and Alkenes: Scope, Stereochemistry, and Asymmetric Catalysis.

✍ Scribed by P. A. WENDER; C. O. HUSFELD; E. LANGKOPF; J. A. LOVE; N. PLEUSS

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

The First Metal-Catalyzed Intramolecular [5 + 2] Cycloadditions of Vinylcyclopropanes and Alkenes: Scope, Stereochemistry, and Asymmetric Catalysis. -This novel cycloaddition works well with a wide variety of substrates, and generally proceeds with exceptional diastereoselectivity and in good to excellent yields. In the presence of chiral phosphine ligands enantioselective cycloaddition is possible. -(WENDER, P. A.; HUSFELD,

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