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ChemInform Abstract: Transformations of the Picrotoxanes: The Synthesis of Corianin and Structural Analogues from Picrotoxinin.

โœ Scribed by M. J. KRISCHE; B. M. TROST

Book ID
101868066
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
29
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Transformations of the Picrotoxanes: The Synthesis of Corianin and Structural Analogues from Picrotoxinin.

-The neurochemically active sesquiterpene corianin (I) and some related compounds are prepared to study structure-activity relationships. -(KRISCHE, M.

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The Palladium-Catalyzed Enyne Cycloisomerization Reaction in a General Approach to the Asymmetric Syntheses of the Picrotoxane Sesquiterpenes. Part 1. First-Generation Total Synthesis of Corianin (V) and Formal Syntheses of Picrotoxinin (VIa) and Picrotin (VIb).