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ChemInform Abstract: Transfer Semihydrogenation of Alkynes Catalyzed by a Zero-Valent Palladium N-Heterocylic Carbene Complex.

✍ Scribed by Peter Hauwert; Giovanni Maestri; Jeroen W. Sprengers; Marta Catellani; Cornelis J. Elsevier

Publisher
John Wiley and Sons
Year
2008
Weight
36 KB
Volume
39
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of Silire
ChemInform Abstract: Synthesis of Silirenes by Palladium-Catalyzed Transfer of Silylene from Siliranes to Alkynes.
✍ W. S. PALMER; K. A. WOERPEL 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

Synthesis of Silirenes by Palladium-Catalyzed Transfer of Silylene from Siliranes to Alkynes. -The title reaction produces thermally stable silirenes such as (III) which can be further react with monosubstituted acetylenes to yield the trisubstituted siloles (V). This reactivity suggests an unusual