ChemInform Abstract: Total Synthesis of (-)-Stellettamide B and Determination of Its Absolute Stereochemistry.
β Scribed by Naoki Yamazaki; Wataru Dokoshi; Chihiro Kibayashi
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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Determination of Relative and Absolute Stereochemistry of Cephalosporolide D and Its Enantioselective Total Synthesis. -The title compound (XI) is synthesized in an efficient approach via an aldol reaction of (II) and (III) as key step. (R)-(I) is obtained from commercially available methyl (R)-3-h