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ChemInform Abstract: Total Synthesis of (S)-(-)-Stepholidine Using (S)-tert-Butanesulfinylimine.

✍ Scribed by Jianjun Cheng; Liqiang Fu; Chenyu Ling; Yushe Yang

Publisher: John Wiley and Sons
Year: 2011
Weight: 41 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201113204

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## Abstract A mild Hendrickson reagent triggered intramolecular cascade cyclization, a highly enantioselective dihydroxylation, and an efficient palladium‐catalyzed migration of O‐allyl to N‐allyl are employed as the key steps in this work.