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ChemInform Abstract: Efficient Total Synthesis of (S)-14-Azacamptothecin.

✍ Scribed by Guan-Sai Liu; Yuan-Shan Yao; Peng Xu; Shaozhong Wang; Zhu-Jun Yao

Publisher
John Wiley and Sons
Year
2010
Weight
16 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

A mild Hendrickson reagent triggered intramolecular cascade cyclization, a highly enantioselective dihydroxylation, and an efficient palladium‐catalyzed migration of O‐allyl to N‐allyl are employed as the key steps in this work.

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