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ChemInform Abstract: Total Synthesis of (+)-Prelaureatin and (+)-Laurallene.

โœ Scribed by Michael T. Crimmins; Elie A. Tabet


Publisher
John Wiley and Sons
Year
2000
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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Conversion of Prelaureatin into Laurallene, a Bromo-Allene Compound, by Enzymatic and Chemical Bromo-Etherification Reactions. -The (E) isomer of prelaureatin is found to react with 2,4,4,6-tetrabromo-2,5-cyclohexadienone and NaBr/H2O2/lactoperoxidase to afford laurallene (II). Starting from the (Z