ChemInform Abstract: Total Synthesis of
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R. HARA; T. FURUKAWA; Y. HORIGUCHI; I. KUWAJIMA
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Article
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2010
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John Wiley and Sons
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Total Synthesis of (ยฑ)-Taxusin. -The synthesis of the title compound (VI) starting from (I) is highlighted by 1.) remarkably effective eight-membered B ring cyclization leading to the C ring allyl ester-type tricyclic taxane skeleton(III) with the desired B ring conformation and C-9/C-10 stereochem