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ChemInform Abstract: Total Synthesis of (.+-.)-Dysibetaine.

✍ Scribed by Jerry Isaacson; Mandy Loo; Yoshihisa Kobayashi

Publisher: John Wiley and Sons
Year: 2008
Weight: 17 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200835177

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Total Synthesis of (±)-Taxusin. -The synthesis of the title compound (VI) starting from (I) is highlighted by 1.) remarkably effective eight-membered B ring cyclization leading to the C ring allyl ester-type tricyclic taxane skeleton(III) with the desired B ring conformation and C-9/C-10 stereochem