Total synthesis of optically active coty
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Nobuo Kato; Hiroaki Okamoto; Hitoshi Takeshita
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Article
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1996
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Elsevier Science
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French
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Starting from condensation of two iridoid synthons, (3S,8R)-benzyloxy-l-iriden-7-al and (3R)-7-chloro-l-iridene, cotylenol, one of the representative fusicoccane diterpenoids having 5-8-5-membered tricyclic carbon framework, is now synthesized for the first time via an eight-membered ring formation