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ChemInform Abstract: Total Synthesis of Clerocidin via a Novel, Enantioselective Homoallenylboration Methodology.

โœ Scribed by A. X. XIANG; D. A. WATSON; T. LING; E. A. THEODORAKIS

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Total Synthesis of Clerocidin via a Novel, Enantioselective Homoallenylboration Methodology. -The key steps in the synthesis of the title compound (VI) are stereoselective homoallenylboration of the aldehyde (II) and regio-and stereoselective epoxidation of the resulting diene (IV). -(XIANG, A. X.; WATSON, D. A.

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Enantioselective Total Synthesis of Taurospongin A. -Taurospongin A (VIII), a naturally occurring fatty acid derivative, is synthesized by using highly effective asymmetric catalytic reactions to set each of the three stereocenter independently. This fact would allow also access to all eight stereoi