Enantioselective Total Synthesis of Taurospongin A. -Taurospongin A (VIII), a naturally occurring fatty acid derivative, is synthesized by using highly effective asymmetric catalytic reactions to set each of the three stereocenter independently. This fact would allow also access to all eight stereoi
ChemInform Abstract: Enantioselective Total Synthesis of Eunicenone A.
β Scribed by Thomas W. Lee; E. J. Corey
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 38 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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Enantioselective Total Synthesis of (+)-Isoboonein. -Starting from the known optically active diol (I), derived via an asymmetric Diels-Alder reaction of dimethyl fumarate with cyclopentadiene, the key intermediate (II) is synthesized via a known approach applied to the racemic series. Further sele