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ChemInform Abstract: Total Synthesis of (-)-Balanol.

โœ Scribed by H. MIYABE; M. TORIEDA; K. INOUE; K. TAJIRI; T. KIGUCHI; T. NAITO

Publisher
John Wiley and Sons
Year
2010
Weight
44 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Total Synthesis of
ChemInform Abstract: Total Synthesis of (-)-Balanol.
โœ H. MIYABE; M. TORIEDA; T. KIGUCHI; T. NAITO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB

Total Synthesis of (-)-Balanol. -The total synthesis of the potent protein kinase C inhibitor is accomplished via a radical cyclization approach to the hexahydroazepine ring (โ†’ (II)), an asymmetric esterification (. fwdarw. (VI)), and a biomimetic route to the benzophenone fragment (. fwdarw. (X)).