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ChemInform Abstract: Total Synthesis of (.+-.)-2-Isocyanoallopupukeanane.

โœ Scribed by Tse-Lok Ho; Liang-Ren Kung; Rong-Jie Chein


Publisher
John Wiley and Sons
Year
2000
Weight
30 KB
Volume
31
Category
Article
ISSN
0931-7597

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Enantiospecific Total Synthesis of (+)-2-Pupukeanone. -The first enantiospecific total synthesis of 2-pupukeanone (X) starting from readily available (R)-carvone (I) is described. Key step in the synthetic sequence is the construction of the tricyclic isotwistane carbon framework via 5-exo-trig rad