ChemInform Abstract: Total Syntheses of (+)- and (-)-1-Deoxynojirimycin (1,5-Dideoxy-1,5-imino-D- and L-glucitol) and of (+)- and (-)-1-Deoxyidonojirimycin (1,5-Dideoxy-1,5-imino-D- and L-iditol) via Furoisoxazoline-3-aldehydes.
β Scribed by Christophe Schaller; Pierre Vogel; Volker Jaeger
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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The protected compounds (V) and (IX) are treated with iodine in MeOH to give pyrrolidines (VI) and (X), respectively. Iodine is found to be an efficient catalyst for deprotection of several O-and N-protecting groups. -(KIM, J.
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