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ChemInform Abstract: TMP-Cadmiate, a Base for Efficient and Chemoselective Deprotonative Metalation Reactions of Aromatic Compounds

โœ Scribed by Florence Mongin; Masanobu Uchiyama


Publisher
John Wiley and Sons
Year
2011
Weight
18 KB
Volume
42
Category
Article
ISSN
0931-7597

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Tungsten Hexachloride (WCl 6 ), a Highly Efficient and Chemoselective Catalyst for Acetalization of Carbonyl Compounds. -Aldehydes and ketones (I) are converted chemoselectively into their corresponding 1,3-dioxanes (V) or diethyl acetals (III) in the presence of catalytic amounts of tungsten hexac