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ChemInform Abstract: Titanocene-Catalyzed Cyclocarbonylation of Enynes to Cyclopentenones.

โœ Scribed by F. A. HICKS; N. M. KABLAOUI; S. L. BUCHWALD

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Titanocene-Catalyze
ChemInform Abstract: Titanocene-Catalyzed Cyclocarbonylation of o-Allyl Aryl Ketones to . gamma.-Butyrolactones.
โœ N. M. KABLAOUI; F. A. HICKS; S. L. BUCHWALD ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 2 views

Titanocene-Catalyzed Cyclocarbonylation of o-Allyl Aryl Ketones to . gamma.-Butyrolactones. -The first catalytic method for the formation of ฮณ-butyrolactones from enones containing an arylketone moiety using Cp2Ti(PMe3)2 or Cp2Ti(CO)2 is developed. The mechanism of this catalytic hetero Pauson-Khan