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ChemInform Abstract: Tin-Mediated Barbier Type Allylation in Ionic Liquids.

✍ Scribed by Rahiem Slaton; Adam Petrone; Renuka Manchanayakage

Publisher
John Wiley and Sons
Year
2011
Weight
30 KB
Volume
43
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Metal-Mediated Barb
ChemInform Abstract: Metal-Mediated Barbier-Type Carbonyl Allylation under Solvent-Free Conditions.
✍ X.-H. YI; J. X. HABERMAN; C.-J. LI πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 1 views

Metal-Mediated Barbier-Type Carbonyl Allylation under Solvent-Free Conditions. -In the title reaction no competing coupling products are observed which could be expected from a free-radical mechanism. A [4 + 2] cycloaddition mechanism is therefore proposed. If zinc or tin is used instead of indium,