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ChemInform Abstract: The Versatile Conversion of Acyclic Amides to α-Alkylated Amines.

✍ Scribed by Young-Ger Suh; Dong-Yun Shin; Jae-Kyung Jung; Seok-Ho Kim

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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Selective Reduction of Secondary Amides to Amines in the Presence of Tertiary Amides. -The transformation is achieved by reduction of secondary amide moieties bearing an activating Cbz group with hydrides. Catalytic hydrogenation of the resulting hemiacetals removes the hydroxyl and the Cbz group t