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ChemInform Abstract: The Utilization of Supercritical Carbon Dioxide in the Palladium-Catalyzed Hydroarylation of β-Substituted-α,β-enones.

✍ Scribed by Sandro Cacchi; Giancarlo Fabrizi; Francesco Gasparrini; Paola Pace; Claudio Villani


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
31
Category
Article
ISSN
0931-7597

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✍ M. BRUNNER; H. ALPER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

The First Stereoselective Palladium-Catalyzed Cyclocarbonylation of β,γ-Substituted Allylic Alcohols. -A catalytic method allowing the synthesis of α,β-substituted-γ-butyrolactones from the title alcohols in modest to good yields is presented. In most cases, this transformation occurs with complete