## Abstract Chlorozinc enolates of (hetero)aryl‐, alkyl‐ and silyl‐substituted acetates were reacted with imines and α‐diimines. The zinc‐mediated reaction of (hetero)aryl‐substituted acetates with imines afforded __trans__‐β‐lactams in good yields and with excellent selectivity. Zinc enolates of n
ChemInform Abstract: The Synthesis of 3-Alkyl- and 3-Aryl-β-lactams from Zinc Enolates and Imines.
✍ Scribed by H. L. VAN MAANEN; H. KLEIJN; J. T. B. H. JASTRZEBSKI; G. VAN KOTEN
- Book ID
- 112022681
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
A new one-pot synthesis of 3-amino-g-lactams that is based on the condensation of simple imines with zinc enolates of disilyl protected glycine esters is mported Isolated yields are high and a rranr-selectivity is observed. ## with imines. With N-(benzylidene)-trimethylsilylamine the ring-closure