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ChemInform Abstract: The Strategy for Co2(CO)8-Catalyzed Double Carbonylative [2 + 2 + 1] Cycloaddition or [2 + 2 + 2] Cycloaddition Reaction of Triynes: A New Synthesis Method for Tetracyclic Compounds.

✍ Scribed by Seung Uk Son; Se-Jung Paik; Sang Ick Lee; Young Keun Chung

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200019045

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A New [4 + 2] Cycloaddition Strategy for the Synthesis of N-Acyl-7-azabicyclo[2.2.1]heptan-2-ones: A Formal Synthesis of (±)-Epibatidine. -The title compound (VIII), an intermediate for the preparation of (±)-epibatidine, is prepared via Diels-Alder reaction of allenes with N-acylated pyrrole (II)

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