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ChemInform Abstract: The Stability of Gold Iodides in the Gas Phase and the Solid State.

✍ Scribed by Tilo Soehnel; Reuben Brown; Lars Kloo; Peter Schwerdtfeger

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
33
Category
Article
ISSN
0931-7597

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Upon treating elemental sulfur with [AgSbF(6)], [AgAl(hfip)(4)], [AgAl(pftb)(4)] (hfip=OCH(CF(3))(2), pftb =OC(CF(3))(3)) the compounds [Ag(S(8))(2)][SbF(6)] (1), [AgS(8)][Al(hfip)(4)] (2), and [Ag(S(8))(2)](+)[[Al(pftb)(4)](-) (3) formed in SO(2) (1), CS(2) (2), or CH(2)Cl(2) (3). Compounds 1-3 wer