ChemInform Abstract: Tautomerism in the Solid State
β Scribed by Tadashi Sugawara; Isao Takasu
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 23 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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Structure and Tautomerism of 3(5)-Amino-5(3)-arylpyrazoles in the Solid State and in Solution: An X-Ray and NMR Study. -The crystal and molecular structures of 5 examples of the title compounds are determined by X-ray analysis. The tautomer (I) is present for R: -H, -O-Me and -Cl, while the tautome
The 13 C cross-polarization magic angle spinning NMR spectra of N-( ) indicate a keto-hydroxy tautomerism of 1 but not of 2. This was confirmed by a single-crystal x-ray diffraction study of 1, which revealed that the two distinct molecules in the unit cell are linked by intermolecular hydrogen bon
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