ChemInform Abstract: The Role of Neighboring Group Participation in TTF-Mediated “Radical-Polar Crossover” Reactions: Trapping of Aliphatic Radicals by TTF+×.

ChemInform Abstract: The Cp2TiPh-Mediate

ChemInform Abstract: The Cp2TiPh-Mediated Reductive Radical Cyclization of Cyanoketones and Related Reactions. Efficient Trapping of Ketyl Radicals by Cp2TiPh-Coordinated Polar Multiple Bonds.

✍ Yoshihiko Yamamoto; Daisuke Matsumi; Reiko Hattori; Kenji Itoh 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 40 KB

The Cp 2 TiPh-Mediated Reductive Radical Cyclization of Cyanoketones and Related Reactions. Efficient Trapping of Ketyl Radicals by Cp 2 TiPh-Coordinated Polar Multiple Bonds. -The Cp 2 TiPh-mediated radical cyclization of cyanoketones in both the 5-and 6-exo modes is successful to provide an easy