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ChemInform Abstract: The Preparation of N-tert-Butyloxycarbonyl-(Boc-)Protected Sulfoximines and Sulfimines by an Iron(II)-Mediated Nitrene Transfer from BocN3 to Sulfoxides and Sulfides.

✍ Scribed by Thorsten Bach; Christina Koerber

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

thio compounds thio compounds (benzene compounds) Q 0590

πŸ“œ SIMILAR VOLUMES

The Preparation of N-tert-Butyloxycarbon
The Preparation of N-tert-Butyloxycarbonyl-(Boc-)Protected Sulfoximines and Sulfimines by an Iron(II)-Mediated Nitrene Transfer from BocN3 to Sulfoxides and Sulfides
✍ Thorsten Bach; Christina KΓΆrber πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 302 KB

The imidation of sulfides and sulfoxides to the corresponding intermediate (nitrene)Fe IV complex is postulated as the reactive nitrene transfer reagent which is formed from FeCl 2 sulfimides and sulfoximides was carried out with N-tertbutyloxycarbonyl azide (BocN 3 ) in the presence of FeCl 2 . an