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ChemInform Abstract: Iron(II)-Mediated Nitrene Transfer from t-Butyloxycarbonyl Azide (BocN3) to Sulfoxides, Sulfides, and Ketene Acetals.

✍ Scribed by T. BACH; C. KOERBER


Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
29
Category
Article
ISSN
0931-7597

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The Preparation of N-tert-Butyloxycarbon
✍ Thorsten Bach; Christina KΓΆrber πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 302 KB πŸ‘ 1 views

The imidation of sulfides and sulfoxides to the corresponding intermediate (nitrene)Fe IV complex is postulated as the reactive nitrene transfer reagent which is formed from FeCl 2 sulfimides and sulfoximides was carried out with N-tertbutyloxycarbonyl azide (BocN 3 ) in the presence of FeCl 2 . an