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ChemInform Abstract: The Mixed Polychalcogenorhenate(IV) Anions [Re4Q4(S3)4 (S4)2]4- (Q: Se, Te): Syntheses and Crystal Structures of [NMe4]5[Me2NH2]3 [Re4Se4(S3)4 (S4)2]2×2.25H2O and [NH4]4 [Re4Te4(S3)4 (S4)2]×8H2O.

✍ Scribed by Yuri V. Mironov; Michael A. Pell; Thomas E. Albrecht-Schmitt; James A. Ibers


Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
32
Category
Article
ISSN
0931-7597

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Coordination Chemistry of [Nb2(S2)2]4+ C
✍ M. Sokolov; A. Virovets; W. Clegg 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 151 KB 👁 2 views

Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space